The Lamb Shift by Saturation Spectroscopy

When you try to obtain very high resolution to examine small splittings in spectral lines, such as the hydrogen fine structure and the Lamb shift, those details are obscured by the sources of line broadening. In a low pressure gas, the main source of broadening is Doppler broadening from the thermal motion of the atoms or molecules of the gas. This is particularly serious in hydrogen, since it has a low mass and therefore high thermal velocity.

Tunable dye lasers are used to excellent advantage in "Doppler-free saturation spectroscopy" to minimize the effects of the Doppler broadening. The light from the laser is split into two beams, a saturating beam and a probe beam, arranged so that they cross in a region of a gas cell containing hydrogen gas. When the laser is tuned to the frequency of an electron transition, the saturating beam is intense enough to deplete the lower level of the transition. The saturating beam is "chopped", or modulated, so that the saturation of the transiton is turned on and off. The probe beam is then absorbed, or not, depending on whether the saturating beam is on. The probe beam strikes a sensitive detector, locked to the modulation frequency, which can then detect a signal at that frequency corresponding to the turning on and off of the absorption of the probe beam. 可调染料激光器在'多普勒自由饱和光谱学'中被很好地利用，以最小化多普勒展宽的影响。激光发出的光被分成两束光，一束是饱和光束，另一束是探测光束，安排成在含有氢气的气体细胞区域内交叉。当激光调谐到电子跃迁的频率时，饱和光束足够强，可以耗尽跃迁的低能级。饱和光束被“切光”，或调制，从而使跃迁的饱和状态被开启和关闭。探测光束然后会被吸收或不被吸收，这取决于饱和光束是否开启。探测光束击中一个敏感的探测器，该探测器锁定在调制频率上，因此可以检测到对应探测光束吸收开启和关闭的信号频率。

The tremendous advantage of this technique for eliminating the effects of Doppler broadening comes from directing the saturation beam and probe beam through the gas in opposite directions. The only hydrogen atoms which are in resonance with both of the beams are those which have no component of velocity in the direction of the beams, and therefore absorb at the frequency associated with the rest frame of the atom. Other atoms in their rest frames see the incoming radiation shifted up for the saturation beam and down for probe beam or vice versa, so they are not resonant for both. The spectrum shown was obtained by tuning the dye laser slowly through the frequency range of the transition and measuring the change in intensity of the probe beam at the modulation or "chopping" frequency.

For hydrogen gas at 300 K, the rms velocity is about 2700 m/s. This speed corresponds to a Doppler shift of about 4 GHz for a hydrogen electronic transition, or a line broadening of twice that. This would effectively obscure the Lamb shift, since it is only 1.057 GHz. This large Doppler broadening was avoided in the Lamb-Retherford experiment by using the microwave transitions where the Doppler shift was small. Using the 2.395 GHz microwaves for the experiment gives a Doppler shift of only about 20 kHz which did not hinder the experiment. This saturation spectroscopy experiment also avoided the Doppler broadening problem.