Of Molecules and Baseballs分子与棒球
The motion of baseballs can reasonably be described by Newton's laws, but the motion of molecules in a gas cannot. It's not that Newton's laws are not as good for gas molecules as baseballs; it's just that we can't track Avogadro's number of them and are forced to use averages or other statistical properties of the collection of molecules. While that might seem to doom us to inaccurate and erratic descriptions of nature, that is definitely not the case. The statistics of very large numbers of events gives a precise description of the collective behavior of the particles. 棒球的运动可以用牛顿运动定律合理地描述,但气体中的分子运动却不能。这并不是说牛顿运动定律对气体分子不如对棒球有效;而是因为我们无法追踪阿伏伽德罗数那么多的分子,只能使用分子集合的平均值或其他统计特性。虽然这似乎使我们陷入对自然的不准确和不规则的描述,但事实并非如此。非常大量的事件的统计特性能够给出粒子集体行为的精确描述。
![]() The field of thermodynamics involves descriptions of phenomena which are too small for us to see. These descriptions are statistical in nature in that they deal with averages over vast numbers of particles. This involves the concepts of internal energy and temperature. It yields relationships like the ideal gas law, equipartition of energy, and specific heat which allow us to make precise predictions about the collective behavior of matter. You can't precisely describe a single molecule like you can a baseball, but the collective behavior of the group is well determined. 热力学这一领域涉及描述那些太小以至于我们无法直接看到的现象。这些描述具有统计性质,因为它们涉及对大量粒子的平均值。这涉及内能和温度的概念。它得出如理想气体定律、能量均分定理和比热这样的关系,使我们能够对物质的集体行为做出精确预测。你无法像预测棒球那样精确地描述单个分子,但群体的整体行为却可以很好地确定。
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Index Internal energy concepts 索引 内能概念 | |||
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