Heat热
Heat may be defined as energy in transit from a high temperature object to a lower temperature object. An object does not possess "heat"; the appropriate term for the microscopic energy in an object is internal energy. The internal energy may be increased by transferring energy to the object from a higher temperature (hotter) object - this is properly called heating. 热量可以定义为从高温物体传向低温物体的能量。一个物体并不具有‘热量’;描述物体中微观能量的适当术语是内能。内能可以通过将能量从高温(更热)物体传递到物体上来增加——这应正确称为加热。
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Index Heat engine concepts 热机概念索引 | ||
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Heat and Work Example热量与功的例子
![]() This example of the interchangeability of heat and work as agents for adding energy to a system can help to dispel some misconceptions about heat. I found the idea in a little article by Mark Zemansky entitled "The Use and Misuse of the Word 'Heat' in Physics Teaching". One key idea from this example is that if you are presented with a high temperature gas, you cannot tell whether it reached that high temperature by being heated, or by having work done on it, or a combination of the two. 这个热和功作为向系统添加能量的等效手段的例子,有助于消除关于热的一些误解。我在这个由Mark Zemansky撰写的短文中找到了这个想法,题为『物理学教学中‘热’这个词的使用与误用』。这个例子的一个关键思想是,如果你面对一个高温气体,你无法确定它是通过加热还是通过对外做功,或者两者的结合使它达到了如此高的温度。
To describe the energy that a high temperature object has, it is not a correct use of the word heat to say that the object "possesses heat" - it is better to say that it possesses internal energy as a result of its molecular motion. The word heat is better reserved to describe the process of transfer of energy from a high temperature object to a lower temperature one. Surely you can take an object at low internal energy and raise it to higher internal energy by heating it. But you can also increase its internal energy by doing work on it, and since the internal energy of a high temperature object resides in random motion of the molecules, you can't tell which mechanism was used to give it that energy. 要描述高温物体所具有的能量,说该物体‘具有热量’是不正确的——更准确的说法是,由于分子运动,该物体具有内能。‘热量’这个词更适合用来描述从高温物体向低温物体传递能量的过程。你当然可以通过加热一个内能较低的物体使其内能增加。你也可以通过对物体做功来增加其内能,而由于高温物体的内能储存在分子的无序运动中,因此无法确定是哪种机制提供了这种能量。
In warning teachers and students alike about the pitfalls of misusing the word "heat", Mark Zemansky advises reflecting on the jingle: 为警示教师和学生避免误用‘热量’一词,Mark Zemansky建议反思以下口诀:
Zemansky points to the First Law of Thermodynamics as a clarifying relationship. The First Law identifies both heat and work as methods of energy transfer which can bring about a change in the internal energy of a system. After that, neither the words work or heat have any usefulness in describing the final state of the sytem - we can speak only of the internal energy of the system. Zemansky指出热力学第一定律是一个澄清的关系。热力学第一定律将热量和功确定为能量传递的两种方法,可以引起系统内能的变化。之后,无论是热量还是功的词语在描述系统的最终状态时都没有用处——我们只能谈论系统的内能。
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Index Internal energy concepts Reference Zemansky 索引 内能概念 参考 Zemansky | |||||
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Mechanical Equivalent of Heat热功当量
Heat flow and work are both ways of transferring energy. As illustrated in the heat and work example, the temperature of a gas can be raised either by heating it, by doing work on it, or a combination of the two. 热量流动和功都是传递能量的方式。如热和功的例子所示,气体的温度可以通过加热它、对它做功,或两者的结合来提高。
In a classic experiment in 1843, James Joule showed the energy equivalence of heating and doing work by using the change in potential energy of falling masses to stir an insulated container of water with paddles. Careful measurements showed the increase in the temperature of the water to be proportional to the mechanical energy used to stir the water. At that time calories were the accepted unit of heat and joules became the accepted unit of mechanical energy. The British Thermal Unit was also introduced. Their relationship to joules is 1843年的一项经典实验中,詹姆斯·焦耳通过利用下落质量的势能来搅拌一个绝热的水容器,展示了加热与做功的能量等效性。精确的测量显示,水温的升高与用来搅拌水的机械能成正比。当时热量的单位是卡路里,而焦耳成为机械能的单位。此外,英热单位也得到了引入。它们与焦耳的关系是
![]() These conversions are the International Steam Table (IT) values, and variations up to 0.5% will be found since they were originally based on energy for temperature changes in water, and that varies a small amount based on what temperature of water is used to establish it. The heat capacity of water does change slightly with temperature. 这些转换值是国际蒸汽表(IT)值,由于它们最初是基于水温变化时的能量确定的,因此可能会有高达0.5%的差异。所用的水温不同,会导致水的热容量有轻微的变化。
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Index Internal energy concepts 索引 内能概念 | ||
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Constant Pressure Work定压功
对于压力 P = Pa = 10^ Pa = atm = mmHg = lb/in²,活塞半径为 r = m 内的位移 d = m 导致体积变化 ΔV= m³ = cm³ = 升。在恒定压力情况下,这对应于功 W = J = 10^ J。 中文译文中的待填/计算数值依次对应:1:p 2:pb 3:pp 4:pat 5:pm 6:pc 7:d 8:r 9:v 10:vcm 11:vl 12:w 13:wb 14:wp。实际数值以上方原输入框为准。 |
Index Heat engine concepts 热机概念索引 | |||
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