Glucose葡萄糖
When oxidized in the body in the process called metabolism, glucose produces carbon dioxide, water, and some nitrogen compounds and in the process provides energy which can be used by the cells. The energy yield is about 686 kilocalories (2870 kilojoules) per mole which can be used to do work or help keep the body warm. This energy figure is the change in Gibbs free energy ΔG in the reaction, the measure of the maximum amount of work obtainable from the reaction. As a primary energy source in the body, it requires no digestion and is often provided intravenously to persons in hospitals as a nutrient. 当葡萄糖在体内通过代谢过程氧化时,会产生二氧化碳、水和一些含氮化合物,并在此过程中提供能量,该能量可以被细胞利用。每摩尔葡萄糖产生的能量约为686千卡(2870千焦),可用于做功或帮助保持体温。这个能量数值是反应的吉布斯自由能变ΔG,它衡量了从该反应中可获得的最大功。作为身体的主要能量来源,葡萄糖不需要消化,常被静脉注射到医院中作为营养补充。
Energy from glucose is obtained from the oxidation reaction 葡萄糖的能量来源于氧化反应
where a mole of glucose (about 180 grams) reacts with six moles of O2 with an energy yield ΔG = 2870 kJ. The six moles of oxygen at STP would occupy 6 x 22.4L = 134 liters. The energy yield from glucose is often stated as the yield per liter of oxygen, which would be 5.1 kcal per liter or 21.4 kJ per liter. This energy yield could be measured by actually burning the glucose and measuring the energy liberated in a calorimeter. 其中,1摩尔葡萄糖(约180克)与6摩尔氧气反应,能量产量ΔG = 2870 kJ。在标准温度和压力下,6摩尔氧气将占据6 × 22.4 L = 134升。葡萄糖的能量产量通常以每升氧气的产量来表示,即每升氧气约5.1千卡或21.4千焦。这种能量产量可以通过实际燃烧葡萄糖并在量热计中测量释放的能量来测定。
But in living organisms, the oxidation of glucose contributes to a series of complex biochemical reactions which provides the energy needed by cells. The first step in the breakdown of glucose in all cells is glycolysis, producing pyruvate which is the starting point for all other processes in cellular respiration. In cells where oxygen is present (aerobic respiration) these processes have been modeled in the TCA or Krebs cycle. A major part of the use of the energy from glucose oxidation is the conversion of ADP to ATP, with the energy-rich molecule ATP being subsequently used as the energy currency of the cell. 但在生物体内,葡萄糖的氧化促进了一系列复杂的生化反应,为细胞提供所需的能量。在所有细胞中,葡萄糖分解的第一步是糖酵解,产生丙酮酸,它是细胞呼吸中所有其他过程的起点。在有氧条件下(有氧呼吸),这些过程在TCA或克雷布斯循环中被建模。葡萄糖氧化所释放的能量的主要用途是将ADP转化为ATP,而能量丰富的分子ATP随后被用作细胞的能量货币。
Glucose is manufactured by plants with the aid of energy from the sun in the process called photosynthesis. This synthesis is carried out in the small energy factories called chloroplasts in plant leaves. The chloroplasts capture the energy from light and fabricate glucose molecules from carbon dioxide from the air and water from the soil. 葡萄糖是由植物利用阳光的能源通过光合作用制造的。这种合成过程发生在植物叶片中的小型能量工厂——叶绿体中。叶绿体捕获光中的能量,并将空气中的二氧化碳和土壤中的水分转化为葡萄糖分子。
C₆H₁₂O₆ + 6O₂ → 6CO₂ + 6H₂O |
Index Biochemical concepts Chemistry concepts References Shipman, Wilson and Todd Ch 15 Tillery, Enger and Ross Ch 14 Tuszynski and Dixon Ch 15 索引 生物化学概念 化学概念 参考文献 Shipman, Wilson 和 Todd 第15章 Tillery, Enger 和 Ross 第14章 Tuszynski 和 Dixon 第15章 | |||||
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Fructose果糖
Fructose is also found in honey. It is classified as the sweetest of all the sugars. 果糖也存在于蜂蜜中。它被归类为所有糖中最为甜的一种。
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Index Biochemical concepts Chemistry concepts References Shipman, Wilson and Todd Ch 15 Tillery, Enger and Ross Ch 14 索引 生物化学概念 化学概念 参考文献 Shipman, Wilson 和 Todd 第15章 Tillery, Enger 和 Ross 第14章 | |||||
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Comparison of Glucose and Fructose葡萄糖与果糖的比较
Glucose and fructose are the two most important simple sugars for human consumption. They have the same molecular formula, C6H12O6, but have different structures. Each is a carbohydrate which can be considered to be the combination of 6 water molecules and 6 carbon dioxide molecules with the yield of 6 oxygen molecules. They are classified differently as hydrocarbon derivatives, glucose being classified as an aldehyde and fructose as a ketone. 葡萄糖和果糖是人类消费的两种最重要的单糖。它们具有相同的分子式,C₆H₁₂O₆,但结构不同。每种都是碳水化合物,可以视为由6个水分子和6个二氧化碳分子结合生成6个氧气分子。它们分别被归类为碳氢化合物衍生物,葡萄糖被归类为醛,果糖被归类为酮。
![]() The sugars differ in the bond environment of the oxygen atom in the sugar. The differences in the functional groups can be seen more clearly in the linear forms below. 糖类在氧原子的键环境上有所不同。在下面的直链形式中,可以更清楚地看到功能基团的差异。
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Index Biochemical concepts Chemistry concepts Tillery,Enger, Ross Ch 14. 索引 生物化学概念 化学概念 Tillery,Enger,Ross 第14章 | ||
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Cellulose纤维素
Cellulose is a form of carbohydrate in which some 1500 glucose rings chain together. It is the chief constituent of cell walls in living organisms. Wood is mostly cellulose, making cellulose the most abundant type of organic compound on the Earth. 纤维素是一种碳水化合物,由约1500个葡萄糖环连接而成。它是活 organisms 细胞壁的主要成分。木材主要由纤维素组成,使纤维素成为地球上最丰富的有机化合物之一。
![]() Cellulose molecules tend to be straight chains, and the fibers which result from collections of cellulose molecules have the strength to form the supporting structures of plants. Even though human digestion cannot break down cellulose for use as a food, animals such as cattle and termites rely on the energy content of cellulose. They have protozoa and bacteria with the necessary enzymes in their digestive systems. Cellulose in the human diet is needed for fiber. 纤维素分子倾向于形成直链,由大量纤维素分子组成的纤维具有形成植物支撑结构的强度。尽管人类无法消化纤维素以供食用,但像牛和白蚁这样的动物依赖纤维素中的能量。它们的消化系统中包含有必要的酶的原生动物和细菌。纤维素在人类饮食中是必需的纤维。
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Index Biochemical concepts Chemistry concepts Tillery,Enger, Ross Ch 14. 索引 生物化学概念 化学概念 Tillery,Enger,Ross 第14章 | ||
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Comparison of Starch and Cellulose淀粉与纤维素的比较
![]() Both starches and cellulose are carbohydrates which are classified as polysaccharides since they are composed of chains of glucose molecules. While they are similar, starches can be used as energy sources by the human body while cellulose cannot. Enzymes are important in the metabolism of foods, and these enzymes are very specific. They are somewhat like keys which will fit the geometry of the starch bonds, but not those of the cellulose bonds. 淀粉和纤维素都是碳水化合物,因为它们由葡萄糖分子链组成,被归类为多糖。虽然它们相似,但淀粉可以被人体用作能量来源,而纤维素则不能。酶在食物代谢中起重要作用,这些酶非常特定。它们 somewhat 像钥匙,能够匹配淀粉键的几何结构,但不匹配纤维素键的几何结构。
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Index Biochemical concepts Chemistry concepts Tillery,Enger, Ross Ch 14. 索引 生物化学概念 化学概念 Tillery,Enger,Ross 第14章 | ||
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